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This letter is in reference to our previous telephone conversation on March 12 regarding hazard evaluation.
Hazard evaluation is a process which relies heavily on the professional judgment of the evaluator. Employers evaluating chemicals shall describe in writing the procedures they used to determine the hazards of the chemical they evaluate. If a determination has been made that a hazard does not exist, then the labeling and material safety data sheet requirements will not apply.
Sincerely,
John B. Miles, Jr., Director Directorate of Field Operations
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Thank you for your letter dated January 28 in regards to the Hazard Communication Standard. Please accept my apology for the delay in response. The overwhelming number of letters and telephone calls regarding the Hazard Communication Standard has caused unavoidable delays in responding to the public's concerns.
Methylene chloride has been shown through established scientific studies to be a suspect carcinogen. However, since the chemical is not listed as a carcinogen by IARC or the NTP, labeling is not listed as a carcinogen by IARC or the NTP, labeling requirements are not necessary.
We currently manufacture a typewriter/printer ribbon that uses methylene chloride in one of the manufacturing processes. Because of the nature of the process, a small amount of residual methylene chloride remains in the ribbon as it is shipped to customers. Currently, the level of methylene chloride in each ribbon is less than 0.1% by weight.
In order to make our manufacturing process more efficient, we are contemplating a change that would raise the residual methylene chloride to a maximum of 0.5% by weight. Extensive airborne monitoring has been performed on typewriters and printers using ribbons with 0.5% to 1% residual methylene chloride. Even under the most extraordinary operating conditions, the highest level of methylene chloride measured at or around the machine is only 0.12 PPM. This is over 4000 times below the current OSHA Permissible Exposure Limit of 500 PPM. Although there have been conflicting studies about the carcinogenicity of methylene chloride, neither IARC nor the latest NTP Annual Report list it as a carcinogen. Since the ribbon is enclosed in a cassette cartridge, this eliminates the need for dermal contact during normal use. Using any of the available exposure criteria for this solvent, we have concluded that there is no inhalation or dermal hazard associated with this ribbon.
In light of the requirements of 29CFR1910.1200, we would like to market this ribbon with a maximum of 0.5% residual methylene chloride without a warning label or Material Safety Data Sheet. We would appreciate your review of our conclusion to ensure that it meets the intent of the Hazard Communication Standard. I would appreciate a written response to this inquiry. If you have any additional questions, please call me at (606) 232-2839.
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Thank you.
ANDERSON, CIH Staff Industrial Hygienist
The original official public domain version of this document is available from OSHA at XXXOSHAURL.